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Kansai University and Murata Manufacturing Co., Ltd. Press Launch

On September 21, Kansai University and Murata Manufacturing Co., Ltd. announced the
development of a sensor device using high-transparency organic piezoelectric film at a press
conference on Senriyama Campus.

Professor Yoshiro Tajitsu, Faculty of Engineering Science, explained the mechanism of
occurrence of piezoelectric phenomenon in the high-transparency organic piezoelectric film, and
described its development method, following an explanation of the sensor device by Mr.
Masamichi Ando, chief researcher at Murata Manufacturing Co., Ltd.

The device will be exhibited at the CEATEC JAPAN 2011, cutting-edge IT & Electronics
comprehensive exhibition, held in Makuhari Messe, Chiba, from October 4 to 8.

Kansai University Press Release(Japanese Only)

For details, please see Murata Manufacturing Co., Ltd. Website.



Professor Yoshiro Tajitsu, Faculty of Engineering Science
Development of Sensor Device Using High-
Transparency Organic Piezoelectric Film

Septemver21,2011

Murata Manufacturing ColLtd.
President,Statutory Representative Director: Tsuneo Murata

Overview

Murata Manufacturing Co., Ltd. has developed a sensor device using high-
transparency organic piezoelectric film. This film has the following
characteristics: (1) high piezoelectric output constant*1; (2) high transparency
(light beam transmittance of 98% or higher [according to the internal haze
measurement]); and (3) free from pyroelectric effect*2. This film can also detect
twisting motion, and therefore there is high expectation for its application to
various human machine interfaces.

Murata has newly developed devices that apply this piezoelectric film, such as a
Leaf Grip Remote Controller that can control the TV using a bending and
twisting motion and a "touch pressure pad," which is a touch panel that can
detect pressure.


Background

As smartphones, tablet computers, and portable game devices become more
widespread, there is a growing demand for a new human/machine interface.
Conventional piezoelectric films are usually subject to a pyroelectric effect,
which is a disadvantage because they cannot detect bending and twisting
vibrations separately from changes in temperature. Murata has developed a
high-transparency piezoelectric film free from pyroelectric effect through joint
research with Kansai University and Mitsui Chemicals Inc.

Applied device

LeafGrip Remote Controller
Leaf Grip Remote Controller using piezoelectric film (sample)

This remote control has a very new conceptual design that enables it to operate
by bending and twisting of a plate made of piezoelectric films that can detect
such motions. Furthermore, it uses pigments to discharge electrons when it
receives light and is assembled with a photovoltaic cell that converts light into
electricity to provide it with a battery-less feature.

Example of use
This remote control can operate a TV by bending or twisting of its plate.

Mechanism


"touch pressure pad" --touch panel with pressure detection

Touch pressure pad using piezoelectric film (sample)

Since this piezoelectric film is not subject to the pyroelectric effect, simply
touching it with a finger does not generate voltage. As a result, the piezoelectric
film is capable of high-precision detection. Furthermore, it can detect finger
movement in the left/right and up/down directions as well as pressing force
(how strongly it is pressed).

Example of use

Pressing the touch panel enlarges the data on the touch panel. This feature can
be used to enlarge data quickly by pressing the panel with a strong force, and
enlarge it slowly by pressing the panel with a weaker force.

Mechanism

We will exhibit these devices and provide demonstrations using these devices at
CEATEC JAPAN 2011 to be held in Makuhari Messe in Chiba Prefecture from
October 4th to 8th.

Terminology

*1 Piezoelectric output      A value obtained by dividing the piezoelectric
constant:                            strain constant by the dielectric constant. This
                                          value is used as an indicator of sensor
                                          sensitivity. When this constant is higher, the
                                          sensor sensitivity is also higher.

*2 Pyroelectric effect:       A change in the temperature changes the
                                          surface electrical charge of dielectrics. The
                                          temperature change can be detected using a
                                          pyroelectric device.

Applications

Displacement sensor (sensor used for detecting bending and twisting)
Touch panel

Electrical Performance

Piezoelectric output constant (g31 180 x 10-3Vm/N
conversion) :

Dielectric constant: 2.5

Sample Shipment

Displacement      Sample shipment planned for spring 2012
sensor:                Note: The timing for commercial application of
                           photovoltaic cells is not yet defined.
Touch panel:       Sample shipment planned for autumn 2012

Patenting Information

Patents pending for approximately 30 items related to materials and applied
devices.
NEWS RELEASE

Teijin & Kansai University Develop New Piezoelectric Material
First Binary-blended Polylactic Acid Multilayer Film with Unprecedented
Piezoelectric Effect

Osaka / Tokyo, Japan, September 6, 2012 --- Teijin Limited and Kansai University
announced today that Teijin’s New Films Development Section and Professor Yoshiro
Tajitsu, Faculty of Engineering Science, Kansai University, have developed a flexible,
transparent piezoelectric material that demonstrates unprecedented piezoelectric
effects.

The piezoelectric effect is the generation of electric power in proportion to the strain
produced when pressure is applied to certain materials, used in impact/vibration
sensors. The inverse piezoelectric effect is the distortion caused by applying electric
power, used in audio speakers, ultrasonic transducers and other actuators that convert
electric energy into motion.

The new material is made with a simple manufacturing process that alternately
laminates two types of polylactic acid (PLA) films: poly-L-lactic acid (PLLA) and optical
isomer poly-D-lactic acid (PDLA). As the world’s first binary-blended PLA multilayer film
with piezoelectric performance that surpasses that of lead zirconate titanate (PZT), a
conventional and widely used piezoelectric material, the new material, which is also
environmentally conscious, is expected to pave the way for larger and more lightweight
products that have been difficult to achieve.


Going forward, the team will continue joint research and development aimed at
achieving a wide range of applications, such as sensors that can detect pressure,
vibration and impact, as well as ultrasonic motors, ultrasonic transducers for medical
care and actuators used in devices such as speakers.

The new material can be manufactured with a simple and practical coextrusion method.
By alternately inserting positive and negative electrodes between PLLA and PDLA films,
which exhibit piezoelectricity motion in opposite directions when exposed to electric
fields of the same direction, the piezoelectricity motion can be aligned in the same
direction. Piezoelectric performance can be controlled by varying the number of layers,
enabling customized designs to suit specific needs.

Research by Professor Tajitsu revealed that when PLA exceeds a certain level of purity,
piezoelectricity improves dramatically. By using high-purity PLLA and PLDA achieved
with Teijin’s advanced PLA refining technology, the new multilayer film demonstrates
superior piezoelectric performance.

In 2006, Teijin developed Biofront, a highly heat-resistant bioplastic with a melting
point of over 210°C, by forming a stereocomplex structure from L-lactic acid and D-lactic
acid. Work on new applications is ongoing.

Background
Until now, inorganic materials have been used widely as piezoelectric materials,
particularly PZT because of its high piezoelectric performance. PZT is a designated
hazardous substance that contains lead, but because there is no other material that can
be used as a substitute, PZT is exempt from the EU directive that restricts the use of
certain hazardous substances in electrical and electronic equipment. Also, because
PZT is a ceramic material, it lacks flexibility and is difficult to increase its size or reduce
its weight.

Polyvinylidene fluoride (PVDF) is an organic-based piezoelectric material, but its action
is weak due to an inverse piezoelectric effect. In addition, because PVDF generates an
electric charge when exposed to heat, it is difficult to use PVDF as a material for
electrical and electronic equipment, so applications are limited to sensors and such. To
achieve piezoelectric effects, a direct-current, high electric field must be applied when
manufacturing PVDF and PZT, so the process has a high energy load.

In contrast, it is widely known that PLA films orient when drawn, so piezoelectric effects
can be generated in a specific direction. However, this effect is short lived and a
practical application level has not been reached. It is also known that when a drawn PLA
film is laminated, the piezoelectric effect increases. However, because deformation
(shearing) into a rhomboid shape occurs due to the piezoelectric effect, it is difficult to
laminate the film into multilayers to generate a piezoelectric effect with a uniform
direction. As a result, it has been difficult to adjust the number of layers, and continuous
production of a multilayer film consisting of single-type PLA films has been a challenge.

About the Teijin Group
Teijin (TSE 3401) is a technology-driven global group offering advanced solutions in the
areas of sustainable transportation, information and electronics, safety and protection,
environment and energy, and healthcare. Its main fields of operation are
high-performance fibers such as aramid, carbon fibers & composites, healthcare, films,
resin & plastic processing, polyester fibers, products converting and IT. The group has
some 150 companies and around 17,000 employees spread out over 20 countries
worldwide. It posted consolidated sales of JPY 854.4 billion (USD 10.7 billion) and total
assets of JPY 762.1 billion (USD 9.5billion) in the fiscal year ending March 31, 2012.
Please visit www.teijin.co.jp/english.

About Kansai University
In 2012, Kansai University celebrated the 126th anniversary of its founding as one of the
leading comprehensive universities in Japan. Kansai University is a prestigious private
university with 13 undergraduate and 12 graduate programs along with 3 professional
graduate schools. There are over 30,000 students enrolled at the university including
more than 700 international students. Kansai University has graduated 400,000
students and they are participating actively in many fields around the world. Kansai
University aims to nurture top runners who can make a contribution to society. We strive
to present the world with new ideas and innovations, and are always dynamic and on
the go.
NEWS RELEASE

Kansai Univ., Teijin Develop World’s First Piezoelectric Fabrics for Wearable Devices

Tokyo, Japan, January 13, 2015 --- Kansai University and Teijin Limited announced
today that Professor Yoshiro Tajitsu, Faculty of Engineering Science, Kansai University,
and Teijin have developed the world’s first polylactic acid (PLA) fiber- and
carbon-fiber-based piezoelectric fabrics.

The new piezoelectric fabrics combine Teijin’s polymer and textile technologies-a Teijin
growth strategy to integrate key existing materials and businesses-with Prof. Tajitsu’s
world-leading knowledge of piezoelectric materials. Development was supervised by
Prof.Tajitsu at Kansai University, with technological cooperation provided by the
Industrial Technology Center of Fukui Prefecture.


New piezoelectric fabrics (from left: plain weave, twill weave and satin weave)


The fabrics comprise a piezoelectric polyctric poly-L-lactic acid (PLLA) and carbon fiber
electrode. Plain, twill and satin weave versions were produced for different applications:
plain weave detects bending, satin weave detects twisting, and twill weave detects
shear and three-dimensional motion, as well as bending and twisting.

The sensing function, which can detect arbitrary displacement or directional changes,
incorporates Teijin’s weaving and knitting technologies. The function allows fabric to be
applied to the actuator or sensor to detect complicated movements, even
three-dimentional movements.

Kansai University and Teijin will introduce the new piezoelectric fabric (booth No. 18-11,
East Hall) at The 1st Wearable Expo, the world’s largest wearable devices and products
exhibition, which will be held at the Tokyo International Exhibition Hall (Tokyo Big Sight) in
Japan from January 14 to 16.

Kansai University and Teijin will continue working on ideal weaves and knits for fabric
applications that enable elaborate human actions to be monitored simply via clothing
worn by people. Such applications are expected to contribute to the evolution of the
Internet of Things (IoT) in fields ranging from elderly care to surgery, artisanal
techniques to space exploration, and many others.

Piezoelectricity is the ability of certain dielectric materials to generate an electric charge
in response to mechanical stress. It also has the opposite effect - the application of
electric voltage produces mechanical strain in the materials. Both of these effects can
be measured, making piezoelectric materials effective for both sensors and actuators.

Lead zirconate titanate (PZT) has practical piezoelectric applications in industry, but as
a ceramic material it lacks transparency and flexibility. In addition, because PZT
contains lead, applications are being increasingly limited by the EU directive that
restricts the use of certain hazardous substances in electrical and electronic equipment.

Polyvinylidene fluoride (PVDF) is a well-known piezoelectric polymer. However, it is
limited to use in sensors and such , and it is not suited to industrial-level manufacturing
because it requires poling treatment and exhibits pyroelectricity. Poling treatment, which
involves applying high DC voltage to a material, is a required process for achieving
piezoelectricity. Pyroelectricity is the ability of certain materials to generate a voltage
and charge following a change in temperature. The existence of pyroelectricity is very
important factor in human-machine interface (HMI) applications because if a
piezoelectric sensor material has pyroelectricity, then it can immediately detect heat
from a finger.

In 2012, Kansai University and Teijin developed a flexible, transparent piezoelectric film
by alternately laminating PLLA and optical isomer poly-D-lactic acid (PDLA). The
all-new wearable piezoelectric fabric announced today is the newest application of this
technology.


CAD data can immediately reflect the folding of a piezoelectric fabric.

About Kansai University
In 2015, Kansai University celebrates the 129th anniversary of its founding as one of the
leading comprehensive universities in Japan. Kansai University is a prestigious private
university with 13 undergraduate and 12 graduate programs along with 3 professional
graduate schools. There are over 30,000 students enrolled at the university including
more than 700 international students. Kansai University has graduated 400,000
students and they are participating actively in many fields around the world. Kansai
University aims to nurture top runners who can make a contribution to society. We strive
to present the world with new ideas and innovations, and are always dynamic and on
the go.

About the Teijin Group
Teijin (TSE: 3401) is a technology-driven global group offering advanced solutions in the
areas of sustainable transportation, information and electronics, safety and protection,
environment and energy, and healthcare. Its main fields of operation are
high-performance fibers such as aramid, carbon fibers & composites, healthcare, films,
resin & plastic processing, polyester fibers, products converting and IT. The group has
some 150 companies and around 16,000 employees spread out over 20 countries
worldwide. It posted consolidated sales of JPY784.4 billion (USD 7.7 billion) and total
assets of JPY 768.4 billion (USD 7.5 billion) in the fiscal year ending March 31, 2014.
Please visit www.teijin.com.

Web News

No.
Contents
Broadcast
Date
1
China Plastic & Rubber Journal
13 September 2012
2
BioBased Digest (US)
11 September 2012
3
Medical Plastics News (UK)
10 September 2012
4
A to Z of Materials (Australia)
7 September 2012
5
BioSpace(US)
13 January 2015
6
IHS Chemical Week(US)
13 January 2015
7
just-style(UK)
14 January 2015
8
fibre2fashion(India)
15 January 2015
9
Innovation in Textiles(UK)
15 January 2015
10
Advanced Textiles Source(US)
6 March 2015

TV News

No.
Contents
Broadcast
Date
1
New remote puts a twist in channel surfing
CBS News(USA)
5 October 2011 0:40
2
Health tech and clever controls at Ceatec
BBC News(UK)
14 October 2011 15:34
3
Tailoring for the Tech Era
NHK World News(JP)
14 January 2015